Country stars were looking their best on the 2012 Grammy Awards red carpet on Sunday night. Married duo Thompson Square walked across the reverent shag first, with Keifer in a faux-alligator jacket and his beautiful wife Shawna sporting a daring but still elegant Basil Soda gown. The couple is nominated for the Best Country Song award, with songwriter and 90s hitmaker David Lee Murphy who also put in an early appearance.

Carrie Underwood looked stunning as she strode down the aisle in her white and silver full-length gown, and Julianne Hough flaunted her beauty in a strapless dress. Scroll through pics from all of country hottest stars who strutted down the red carpet at the 2012 Grammy Awards, and keep checking back throughout the evening to see more from the festivities.