Country duo Love and Theft are making an appearance on the new ABC series 'GCB' on Sunday (April 29) where they will perform their hit single 'Angel Eyes.' In the clip below, you can see the band's Stephen Barker Liles and Eric Gunderson performing on a stage before a giant banner that reads "Dallas Interfaith Barbeque Invitational." As the song plays, all the GCBs enter the scene in quite a dramatic moment, apparently taking part in the invitational with their barbeque team known as the "Spicy Racks."

The scene fits well with the lyrics to the Love and Theft song: "There’s a little bit of devil in her angel eyes / She’s a little bit of heaven with a wild sideGot a rebel heart a country mile wideThere’s a little bit of devil in her angel eyes."

Both Liles and Gunderson said appearing on the show was a fun experience they won't soon forget. "Performing 'Angel Eyes' on 'GCB' was definitely a killer experience," Liles said in a press release. "I started watching the show from episode one and I really love it. I grew up a preacher's kid so I can closely relate to a lot of the dialogue. We are thrilled to be involved with such a fun new show!"

Gunderson seemed equally pleased with his experience, saying, "Being a part of 'GCB' was a blast. The cast was so easy to work with and they made us feel right at home. It was cool to see the film side of the entertainment business and get a taste of what acting is all about."

Be sure to catch the guys performing on 'GCB' on ABC Sunday, April 29 at at 10PM ET.

Watch Clip of Love and Theft Performing on 'GCB'