The breakout hit for husband and wife duo Thompson Square became one of the most sought-after singles on iTunes in 2011 on its way to No. 1 and an armful of major award nominations. What makes this song so remarkable -- and a must have on the list of  Top 100 Country Love Songs -- is that it works to be nothing more than a sweet, simple story of one long-lasting relationship. There's no syrup or drama, just two people nervous in love.

"When the preacher man said, 'Say I do' / I did and you did too / Then I lifted that veil and saw your pretty smile / And I said 'Are you gonna kiss me or not,'" they sing together.

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Listen to Thompson Square, 'Are You Gonna Kiss Me or Not'